Chiral complexes prepared in situ from cinchona alkaloids and metal salts were applied to the catalytic asymmetric reduction of acetophenone for the first time.
金鸡纳生物碱的金属络合物用于苯乙酮的不对称催化还原刘湘(无锡轻工大学化工系无锡214036)李纪国张正(南京大学化学系南京210093)关键词金鸡纳生物碱手性络合物不对称还原苯乙酮分类号O643。
A chiral complex, in situ prepared from (-)quinine and CoCl2 was used as catalyst for asymmetric reduction of aromatic prochiral ketones: pR2C6H4COR1 (R1, R2 shown in Tab.
奎宁与钴(Ⅱ)手性络合物用于前手性酮的不对称催化还原刘湘*李纪国张正(无锡轻工大学化工系无锡214036)(南京大学化学系南京)关键词手性络合物,不对称还原,前手性芳香酮1996-10-25收稿,1997-04-22修回前手性酮的不对。
Based on the theory of reactive extraction,the new neutral complexing extraction systems (EFM 1 and diluent) for the extraction of meleumycin was studied in detail.
从反应萃取的机理出发,以麦白霉素的萃取为例讨论了中性络合萃取体系。
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