Endothermic aqueous-phase reforming of methanol for hydrogen generation and exothermic hydrogenation of acetophenone to α-phenylethanol can be performed over the same type of catalyst under similar conditions (temperature and pressure).
据此,提出利用甲醇水相重整制氢原位还原苯乙酮制备α-苯乙醇,将两个反应偶合形成一种新的苯乙酮加氢还原方法,即苯乙酮液相原位加氢还原法。
β-Phenylethanol (also known as 2- phenylethanol and PEA) is aromatic alcohols with the aroma of roses.
二、苯乙醇是最为广用的大宗香料之一,现世界年产量估计在1万吨左右,仅次于香兰素。
The asymmetric reduction of acetophenone(ACP) to chiral α-phenylethyl alcohol(PEA) in an aqueous phase catalyzed by Saccharomyces cerevisiae cells was studied as a model reaction.
实验发现,酵母细胞催化苯乙酮不对称还原的产物以(S)-α-苯乙醇为主,反应的立体选择性很高,(S)-α-苯乙醇的对映体过量值可达99%左右。
Determination of 2-phenylethanol in Fermented Liquid by Ultraviolet Spectrophotometry;
紫外分光光度法测定发酵液中的2-苯乙醇含量
Breeding of Yeast Strain for Production of 2-phenylethanol by Biotransformation;
生物转化法合成2-苯乙醇菌种的诱变选育
Progress in 2-phenylethanol Production by Biotransformation with Yeast;
酵母生物转化生产2-苯乙醇的研究进展
Study on Asymmetric Transfer Hydrogenation of Acetophenone in Water;
苯乙酮不对称还原为手性α-苯乙醇的研究
In-Situ Reduction of Acetophenone to α-Phenylethanol with Hydrogen from Aqueous-Phase Reforming of Methanol;
甲醇水相重整制氢原位还原苯乙酮制备α-苯乙醇
Biotransformation of L-phenylalanine to 2-phenylethanol by Microorganism;
微生物转化L-苯丙氨酸生成2-苯乙醇的研究
Studies on the Production of 2-Phenylethanol by Transformation with Yeast;
酵母生物转化生产2-苯乙醇的研究
Study on the Biotransformation of 2-phenylethanol by Saccharomyces Cerevisiae
酿酒酵母转化法生产2-苯乙醇的研究
Enzymatic Synthesis of 2-Chloro-l-Phenylethanol with High Optical Purity
高光学纯度2-氯-1-苯乙醇的酶法合成
Phenobarbital diethylaminoethanol
苯巴比妥-二乙基氨乙醇
The Alkylation of Benzene With Ethanol Over Zeolite HZSM-5
HZSM-5沸石上苯与乙醇烷基化合成乙苯
polyethylene glycol terephthalate
聚对苯二甲酸乙二醇酯
ethylene terephthalate
对苯二甲酸乙二[醇]酯
styrenated alkyd
苯乙烯改性醇酸树脂
Glycol monomethyl ether, propylene glycol monomethyl ether, ethanol, and eth yleneglycol monophenylether were used as solvents.
选择丙二醇甲醚,乙二醇甲醚,丙醇,一半乙二醇甲醚一半乙醇,乙二醇苯醚作为溶剂。
Solubility:Soluble in methanol, ethanol. Hardly soluble in toluene, xylene.
溶解度:溶于甲醇、乙醇。难溶于甲苯、二甲苯。
EMGP (Ethylmethylglycol Phthalate)
邻苯二甲酸乙基甲基乙二醇酯
hylene etheralcohol
乙基二甲苯聚氧乙烯醚醇
Catalytic Synthesis of Ethylene Glycol Diacetate with ρ-Toluene Sulpthonic Acid;
对甲苯磺酸催化合成二乙酸乙二醇酯
The catalytic activity of styrene-divinyl benzene resin supported binuclear cobalt phthalocyanine on 2-mercaptoethanol
苯乙烯-二乙烯苯树脂负载双核钴酞菁对巯基乙醇的催化性能
Study on Direct Esterification of PTA with BG and EG
对苯二甲酸与丁二醇和乙二醇直接酯化的研究
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