Synthesis Characteriazation and XPS Study of Diethyl Sulfoxide Complexes of Lanthanide Hexafluorophosphates;
镧系元素六氟磷酸盐二乙基亚砜配合物的合成表征及X-光电子能谱研究
The synthesis of the fifteen diethyl sulfoxide complexes of crytalline lan- thanide hexafluorophosphate in methyl is reported in this paper.
本文在无水甲醇溶剂中合成了十五个新的镧系元素二乙基亚砜配合物,并对其进行了组成分析、X射线粉末衍射、红外光谱、光电子能谱、摩尔电导测定,确定其化学结构式为Ln(DES-O)_n(PF_6)_3〔Ln=La,n=7。
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